College Board · AP Chemistry

AP Chemistry: Thermodynamics — Practice Questions & Answers

Track energy as heat in chemical and physical changes using calorimetry, enthalpy, bond energies, formation data, and Hess's law.

540 practice questions available for this unit — here are 10 with full answers and explanations.

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Practice questions with answers

1 Multiple choice · Easy

Which of the following best describes an exothermic process?

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WhyAn exothermic process releases energy to the surroundings, so the enthalpy change is negative and the surroundings warm up.
2 Multiple choice · Easy

On a reaction energy (potential energy) diagram, an endothermic reaction is shown when the products are located:

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WhyIn an endothermic reaction the products have higher potential energy than the reactants, so energy is absorbed overall.
3 Multiple choice · Easy

When two objects at different temperatures are placed in contact and reach thermal equilibrium, this means:

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WhyAt thermal equilibrium both objects are at the same temperature and there is no net flow of heat between them.
4 Multiple choice · Easy

Which phase change is endothermic?

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WhyMelting (fusion) requires energy input to overcome intermolecular forces, so it is endothermic. Freezing, condensation, and deposition release energy.
5 Multiple choice · Easy

In the equation q = mc*deltaT, the symbol c represents:

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WhyThe symbol c is the specific heat capacity, the energy needed to raise the temperature of 1 gram of substance by 1 degree Celsius.
6 Fill in the blank · Easy

The standard enthalpy of formation of any element in its most stable form, such as O2(g) or C(graphite), is equal to kJ/mol.

Answer: 0 / zero

WhyBy definition, the standard enthalpy of formation of an element in its standard state is zero because no reaction is needed to form it from itself.
7 Multiple choice · Medium

A 50.0 g sample of water (c = 4.18 J/(g*C)) is heated from 20.0 C to 60.0 C. How much heat is absorbed?

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Whyq = mc*deltaT = 50.0 * 4.18 * 40.0 = 8360 J = 8.36 kJ.
8 Multiple choice · Medium

Breaking chemical bonds and forming chemical bonds have which energy characteristics?

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WhyBreaking bonds always requires energy input (endothermic) while forming bonds always releases energy (exothermic).
9 Multiple choice · Medium

A reaction has delta H = -92 kJ/mol. If the reaction is reversed, the enthalpy change of the reverse reaction is:

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WhyReversing a reaction changes the sign of delta H, so the reverse reaction has delta H = +92 kJ/mol.
10 Multiple choice · Medium

A metal sample releases 500 J of heat as it cools by 25.0 C. If the metal has a mass of 40.0 g, what is its specific heat capacity?

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Whyc = q / (m*deltaT) = 500 / (40.0 * 25.0) = 0.500 J/(g*C).

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Key terms in Thermodynamics

Thermodynamics: The study of energy and its transformations during physical and chemical processes.
Energy: The capacity to do work or transfer heat.
System: The specific part of the universe being studied in a thermodynamic process.
Surroundings: Everything outside the system that can exchange energy with it.
Heat: Energy transferred between a system and its surroundings due to a temperature difference, symbolized q.
Work: Energy transferred when a force moves an object through a distance, symbolized w.
Temperature: A measure of the average kinetic energy of the particles in a sample.
Thermal energy: The total kinetic energy of all particles in a substance due to their random motion.

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