One mole of methane is allowed to react with two moles of chlorine in the presence of light. Which best describes the organic product(s)?
a mixture containing CH3Cl, CH2Cl2, CHCl3 and CCl4
one mole of CCl4
one mole of CH2Cl2
a mixture containing only CCl4 and CH2Cl2
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WhyChlorination of methane occurs stepwise, giving a mixture of all four chloromethanes.
2Multiple choice · Medium
The reaction of methane with chlorine under ultraviolet light is classified as a
substitution reaction
addition reaction
condensation reaction
neutralisation reaction
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WhyHydrogen atoms are substituted by chlorine atoms.
3Multiple choice · Hard
Why does ethene, unlike methane, react with chlorine without UV light?
ethene has a C=C double bond that undergoes addition
ethene is saturated
ethene is a smaller molecule
ethene is more volatile
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WhyEthene undergoes rapid addition across its C=C bond, whereas methane needs UV for substitution.
4Fill in the blank · Easy
Replacing hydrogen atoms of an alkane with chlorine atoms under light is a reaction.
Answer:
substitution
WhyIt is a photochemical substitution.
5Fill in the blank · Medium
Alkanes contain only single bonds, so they are hydrocarbons.
Answer:
saturated
WhySaturated hydrocarbons have no C=C bonds.
6Fill in the blank · Hard
The condition required for the reaction between methane and chlorine is light.
Answer:
ultraviolet / UV
WhyUV light initiates the substitution.
7Multiple choice · Medium
Petrol can be obtained from petroleum by fractional distillation. At the molecular level this works because the hydrocarbon molecules in petroleum have
different chain lengths and so different boiling points
the same boiling point
different numbers of protons
ionic structures
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Whydifferent chain lengths and therefore different boiling points.
8Multiple choice · Easy
Besides fractional distillation, extra petrol can be produced from heavier fractions by
cracking
electrolysis
neutralisation
condensation polymerisation
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Whycracking.
9Multiple choice · Hard
Larger hydrocarbon molecules have higher boiling points because
they have stronger van der Waals' forces between molecules
they have stronger covalent bonds
they are ionic
they are more reactive
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Whythey have more electrons, giving stronger van der Waals forces between molecules.
10Fill in the blank · Medium
Fractional distillation separates petroleum into fractions according to differences in point.
Answer:
boiling
WhyBoiling point.
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