DSE Chemistry

DSE Chemistry: Redox Reactions, Chemical Cells and Electrolysis — Practice Questions & Answers

Oxidation numbers and redox in terms of electron transfer, displacement reactions, simple and galvanic chemical cells, electrolysis, and electroplating.

456 practice questions available for this topic — here are 10 with full answers and explanations.

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Practice questions with answers

1 Multiple choice · Medium

What is the oxidation number of Cu in Cu(NH3)4Cl2?

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WhyNH3 is neutral and the two Cl contribute -2 in total, so Cu is +2.
2 Multiple choice · Medium

What is the oxidation number of Mn in MnO4-?

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WhyFour O at -2 give -8; for an overall -1, Mn is +7.
3 Multiple choice · Easy

The oxidation number of oxygen in a peroxide such as H2O2 is

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WhyIn peroxides oxygen takes the unusual value of -1.
4 Fill in the blank · Medium

In the sulphate ion SO4 2-, the oxidation number of sulphur is +.

Answer: 6 / six

WhyFour O at -2 give -8; overall -2, so S = +6.
5 Fill in the blank · Easy

A species is oxidised when its oxidation number during a reaction.

Answer: increases / rises / goes up

WhyOxidation = increase in oxidation number.
6 Fill in the blank · Medium

The oxidation number of hydrogen is +1 in most compounds, but it is in metal hydrides such as NaH.

Answer: -1 / minus 1

WhyThis is a standard exception to remember.
7 Multiple choice · Medium

The tendency of being reduced of six ionic species increases in the order Ba2+(aq) < Na+(aq) < Mg2+(aq) < H+(aq) < Cu2+(aq) < Hg2+(aq). Which statement is correct?

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WhyA species lower in this order (such as Na/Na+) corresponds to a metal with stronger reducing power than Hg.
8 Multiple choice · Medium

Which of the following displacement reactions can occur?

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WhyZinc is more reactive than copper, so it displaces copper from copper(II) sulphate.
9 Multiple choice · Easy

In the reaction Mg(s) + Cu2+(aq) -> Mg2+(aq) + Cu(s), the Cu2+ ion acts as

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WhyCu2+ gains electrons (is reduced), so it is the oxidising agent.
10 Fill in the blank · Medium

A reducing agent gives electrons to another species and is itself .

Answer: oxidised / oxidized

WhyThe reducing agent undergoes oxidation.

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Key terms in Redox Reactions, Chemical Cells and Electrolysis

Oxidation: The loss of electrons by a species, or an increase in its oxidation number.
Reduction: The gain of electrons by a species, or a decrease in its oxidation number.
Redox reaction: A reaction in which electrons are transferred, with oxidation and reduction occurring together.
Oxidising agent: A species that accepts electrons and is itself reduced in a redox reaction.
Reducing agent: A species that donates electrons and is itself oxidised in a redox reaction.
Oxidation number: A number assigned to an atom representing the charge it would have if bonds were ionic.
Half-equation: A balanced equation showing only the oxidation or only the reduction part of a redox reaction.
Chemical cell: A device that converts chemical energy from a spontaneous redox reaction into electrical energy.

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